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6-Aminopenicillanic acid | 551-16-6
551-16-6

Product Name:6-Aminopenicillanic acid

CAS No:551-16-6
MF:C8H12N2O3S
MW:216.2575
MDL:MFCD00005176
CID:38267
PubChem ID:11082
Introduction
6-Aminopenicillanic acid (6-APA) 是合成 β-内酰胺抗生素的重要前体。6-Aminopenicillanic acid 是青霉素 G (PenG) 被青霉素酰基转移酶 (PA) 水解的主要产物。
Names and Identifiers
  • 6-Aminopenicillanic acid
  • 6-APA
  • 4-Thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid, 6-amino-3,3-dimethyl-7-oxo-, [2S-(2alpha,5alpha,6beta)]-
  • 6-Amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid
  • aminopenicillanic acid
  • (+)-6-Aminopenicillanic Acid
  • (2S,5R,6R)-6-AMino-3,3-diMethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid
  • 6-Amino
  • 6-AMINO PENICILLINIC ACID
  • 6-Aminopenicillansure
  • 6-aps
  • AMoxicillin Related CoMpound A
  • penicin
  • penin
  • Mesosulli
  • Cefdinir Impurity H
  • Phenacyl 6-aminopenicillinate
  • 6-Aminopenicillamine acid
  • 6-aminopenicillanate
  • 6-Aminopenicillanicacid
  • QR0C4R7XVN
  • 6beta-aminopenicillanic acid
  • (2S,5R,6R)-6-Amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo(3.2.0)heptan-2-carbon
  • Ampicillin EP impurity A
  • SCHEMBL66332
  • CHEMBL1236749
  • CLOXACILLIN SODIUM IMPURITY C [EP IMPURITY]
  • (2S,5R,6R)-(+)-6-Amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid
  • NCGC00160198-01
  • 6-amino-2,2-dimethylpenam-3alpha-carboxylic acid
  • AI3-52557
  • AMOXICILLIN SODIUM IMPURITY A [EP IMPURITY]
  • DTXSID7046097
  • BENZYLPENICILLIN POTASSIUM IMPURITY A [EP IMPURITY]
  • DTXCID5026097
  • (2S)-6-amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid
  • PHENOXYMETHYLPENICILLIN IMPURITY C [EP IMPURITY]
  • KS-5277
  • A830497
  • (2S,5R,6R)-6-Amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo(3.2.0)heptan-2-carbonsaeure
  • NSC-50071
  • EC 208-993-4
  • AC-11282
  • 6beta-amino-2,2-dimethylpenam-3alpha-carboxylic acid
  • EINECS 208-993-4
  • SR-01000640154-1
  • MFCD00005176
  • s5035
  • 4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid, 6-amino-3,3-dimethyl-7-oxo-, (2S,6R)-
  • (2S,5R,6R)-6-amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylicacid
  • AMOXICILLIN TRIHYDRATE IMPURITY A [EP IMPURITY]
  • (3S, 5R, 6R)-6-amino-2,2-dimethylpenam-3-carboxylic acid
  • OXACILLIN SODIUM MONOHYDRATE IMPURITY A [EP IMPURITY]
  • STR03060
  • A0800
  • Q2823234
  • 6-aminopenicillinic acid (6-APA)
  • HY-W013549
  • (2S,5R,6R)-6-Amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic Acid (6-Aminopenicillanic Acid)
  • bmse000312
  • FLUCLOXACILLIN SODIUM MONOHYDRATE IMPURITY C [EP IMPURITY]
  • 4-Thia-1-azabicyclo(3.2.0)heptane-2-carboxylic acid, 6-amino-3,3-dimethyl-7-oxo-, (2S,5R,6R)-
  • UNII-QR0C4R7XVN
  • (2S,5R,6R)-6-AMINO-3,3-DIMETHYL-7-OXO-4-THIA-1-AZABICYCLO(3.2.0)HEPTANE-2-CARBOXYLIC ACID
  • AKOS015907713
  • amino penicillanic acid
  • Flucloxacillin impurity C, European Pharmacopoeia (EP) Reference Standard
  • PHENOXYMETHYLPENICILLIN (BENZATHINE) TETRAHYDRATE IMPURITY C [EP IMPURITY]
  • rel-(2R,6S)-6-amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid
  • W-105586
  • CAS-551-16-6
  • 551-16-6
  • 6-aminopenici llanic acid
  • AMPICILLIN TRIHYDRATE IMPURITY A [EP IMPURITY]
  • X1E
  • (+)-6-Aminopenicillanic acid, 96%
  • 6-APA (2S,5R,6R)-6-Amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid Penicin Penin
  • Epitope ID:117703
  • EN300-114057
  • AMPICILLIN IMPURITY A [EP IMPURITY]
  • NGHVIOIJCVXTGV-ALEPSDHESA-N
  • FLUCLOXACILLIN MAGNESIUM OCTAHYDRATE IMPURITY C [EP IMPURITY]
  • NSC 50071
  • PHENOXYMETHYLPENICILLIN POTASSIUM IMPURITY C [EP IMPURITY]
  • 6-aminopenicillanic-acid
  • 6-AMINOPENICILLANIC ACID [MI]
  • BCP13375
  • PIPERACILLIN SODIUM IMPURITY H [EP]
  • 4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid, 6-amino-3,3-dimethyl-7-oxo-, (2S,5R,6R)-
  • Z1269203097
  • [2S-(2alpha,5alpha,6beta)]-6-Amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid
  • BDBM50420257
  • CHEBI:16705
  • (3S,5R,6R)-6-amino-2,2-dimethylpenam-3-carboxylic acid
  • 09070_FLUKA
  • BENZYLPENICILLIN SODIUM IMPURITY A [EP IMPURITY]
  • CS-W014265
  • 6-amino-penicillanic acid
  • C02954
  • Tox21_111749
  • DICLOXACILLIN SODIUM IMPURITY C [EP IMPURITY]
  • NS00011463
  • s12351
  • SULBACTAM SODIUM IMPURITY B [EP IMPURITY]
  • (+)-6-Aminopenicillanic acid, analytical standard
  • CCG-50809
  • Amoxicillin Trihydrate Imp. A
  • Penicillin EP impurity A
  • Piperacillin Impurity H
  • BRD-K30284967-001-01-8
  • MDL:MFCD00005176
  • InChIKey:NGHVIOIJCVXTGV-ALEPSDHESA-N
  • Inchi:1S/C8H12N2O3S/c1-8(2)4(7(12)13)10-5(11)3(9)6(10)14-8/h3-4,6H,9H2,1-2H3,(H,12,13)/t3-,4+,6-/m1/s1
  • SMILES:S1C(C([H])([H])[H])(C([H])([H])[H])[C@]([H])(C(=O)O[H])N2C([C@]([H])([C@@]12[H])N([H])[H])=O
  • BRN:15080
Chemical and Physical Properties

Computed Properties

  • Exact Mass: 216.26g/mol
  • Surface Charge: 0
  • XLogP3: -2.1
  • Hydrogen Bond Donor Count: 2
  • Hydrogen Bond Acceptor Count: 5
  • Rotatable Bond Count: 1
  • Exact Mass: 216.056863g/mol
  • Monoisotopic Mass: 216.056863g/mol
  • Topological Polar Surface Area: 109Ų
  • Heavy Atom Count: 14
  • Complexity: 318
  • Isotope Atom Count: 0
  • Defined Atom Stereocenter Count: 3
  • Undefined Atom Stereocenter Count: 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Covalently-Bonded Unit Count: 1
  • 表面电荷: 0

Experimental Properties

  • LogP: 0.09880
  • PSA: 108.93000
  • Merck: 458
  • 折射率: 1.6300 (estimate)
  • 水溶性: Soluble in water and hydrochoric acid.
  • 沸点: 460.2°C at 760 mmHg
  • 熔点: 198-200 °C (dec.) (lit.)
  • 闪点: 232.1°C
  • 溶解度: 2.46g/l
  • 颜色与性状: Powder
  • PH值: 3.4 (100g/l, H2O)
  • 溶解性: 微溶于水,不溶于乙酸丁酯、乙醇或丙酮
  • 比旋光度: 276.3 º (c=1.2, 0.1N HCl 22 ºC)
  • 光学活性: [α]22/D +276.3°, c = 1.2 in 0.1 M HCl
  • 密度: 1.3418 (rough estimate)
Security Information
  • Symbol: GHS08 GHS08
  • RTECS号:XH8225000
  • WGK Germany:2
  • 安全术语:S24;S37;S45
  • 安全说明:S22-S36/37-S45-S37-S24
  • 风险术语:R42/43
  • 危險品標誌: Xn Xn
  • 危险品运输编号:NONH for all modes of transport
  • 危害声明:H317,H334
  • 警示性声明:P261,P280,P342+P311
  • 提示语:危险
  • 储存条件:2-8°C
  • 危险类别码:R42/43
  • 信号词:Danger
  • TSCA:Yes
  • FLUKA BRAND F CODES:10
Customs Data
  • 海关编码:2941109300
  • 海关数据:

    中国海关编码:

    2941109300

    概述:

    2941109300. 6氨基青霉烷酸(6APA). 增值税率:17.0%. 退税率:13.0%. 监管条件:Q(进口药品通关单). 最低关税:4.0%. 普通关税:20.0%

    申报要素:

    品名, 包装

    Summary:

    2941109300. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:Q(report of inspection of soundness on import medicines). MFN tariff:4.0%. General tariff:20.0%

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S17128-500gBR,98%上海:4/北京:0/武汉:0/南京:0500g¥850.0002 Sep. 2021
S17128-500gBR,98%上海:4/北京:0/武汉:0/南京:0500g¥520.0015 Sep. 2023
S17128-100gBR,98%上海:6/北京:3/武汉:2/南京:0100g¥190.0015 Sep. 2023
S17128-25gBR,98%上海:4/北京:0/武汉:0/南京:025g¥50.0015 Sep. 2023
S17128-5gBR,98%上海:>10/北京:0/武汉:0/南京:05g¥30.0015 Sep. 2023
Brand:xlswSupplier:云南西力生物技术股份有限公司
No.PurityStockSpecificationPriceupdate timeoperate
BBP80972-5mg98.0%5mg¥10007 May. 2021
BBP80972-20mg98.0%20mg¥30019 Sep. 2023
Brand:aaronSupplier:Aaron
No.PurityStockSpecificationPriceupdate timeoperate
AR00350O-500g95%In China Stock500g$67.0013 Dec. 2023
AR00350O-100g95%In China Stock100g$16.0013 Dec. 2023
AR00350O-25g95%In China Stock25g$5.0013 Dec. 2023
AR00350O-5g95%In China Stock5g$4.0013 Dec. 2023
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