Safety information identification description

Risk statement
HAZARD STATEMENTS
Risk statement

There are 72 separate and 17 combined hazard statements
There are 72 individual and 17 combined Hazard statements

Physical hazard Physical hazards

H200 Unstable explosives Unstable explosives.
H201 Explosive; mass explosion hazard Explosives; large-scale explosion hazard.
H202 Explosive, severe projection hazard Explosives; serious jet hazard.
H203 Explosive; fire, blast or projection hazard Explosives; fire, explosion or jet hazard.
H204 Fire or projection hazard Fire or spray hazard.
H205 May mass explode in fire A large explosion may occur in the fire.
H220 Extremely flammable gas Very flammable gas.
H221 Flammable gas Flammable gas.
H222 Extremely flammable aerosol Extremely flammable aerosol
H223 Flammable aerosol Flammable aerosol
H224 Extremely flammable liquid and vapour Extremely flammable liquid and vapour
H225 Highly flammable liquid and vapour Highly flammable liquid and vapour
H226 Flammable liquid and vapour Flammable liquid and vapour
H227 Combustible liquid Flammable liquid
H228 Flammable solid Flammable solid
H240 Heating may cause an explosion Heating may cause an explosion
H241 Heating may cause a fire or explosion Heating may cause fire or explosion
H242 Heating may cause a fire Heating may cause a fire
H250 Catches fire spontaneously if exposed to air Exposure to air spontaneously on fire
H251 Self-heating: may catch fire Self-heating: may catch fire
H252 Self-heating in large quantities; may catch fire The self releases a lot of heat; it may catch fire.
H260 In contact with water releases flammable gases which may ignite spontaneously Releases combustible gas when in contact with water and is self-igniting.
H261 In contact with water releases flammable gas Releases flammable gases when in contact with water.
H270 May cause or intensify fire; oxidizer May cause or exacerbate combustion; oxidants.
H271 May cause fire or explosion; strong oxidizer May cause fire or explosion; strong oxidizer.
H272 May intensify fire; oxidizer May exacerbate the fire; oxidants.
H280 Contains gas under pressure; may explode if heated Contains high pressure gas and may explode if exposed to heat.
H281 Contains refrigerated gas; may cause cryogenic burns or injury Contains frozen gas, which may cause low temperature burns or damage.
H290 May be corrosive to metals May corrode metals.

Environmental hazard Environmental Hazards

H400 Verytoxictoaquaticlife Very toxic to aquatic life.
H401 Toxictoaquaticlife Toxic to aquatic life.
H402 Harmfultoaquaticlife Harmful to aquatic life.
H410 Verytoxictoaquaticlifewithlonglastingeffects Very toxic to aquatic life with long-term effects.
H411 Toxictoaquaticlifewithlonglastingeffects It is toxic to aquatic organisms and has long-term effects.
H412 Harmfutoaquaticlifewithlonglastingeffects Harmful to aquatic life with long-term effects.
H413 Maycauselonglastingharmfuleffectstoaquaticlife May cause long-lasting harmful effects on aquatic life.
H420 Harmspublichealthandtheenvironmentbydestroyingozoneintheupperatmospere Harm the public health and the environment by destroying the upper atmosphere ozone layer.

EU hazard statement European Union Hazard Statements

EUH001 Explosive when dry. Explosive when dry.
EUH006 Explosive with or without contact with air. Contact or no contact with air explosion
EUH014 Reacts violently with water. Reacts violently with water.
EUH018 In use may form flammable/explosive vapour-air mixture. A flammable/explosive vapor-air mixture may form during use.
EUH018a In use may form explosive vapour-air mixture. An explosive vapor-air mixture may form during use.
EUH018b In use may form flammable vapour-air mixture. A flammable vapor-air mixture may form during use.
EUH019 May form explosive peroxides. An explosive peroxide can be formed.
EUH029 Contact with water liberates toxic gas. Contact with water releases toxic gases.
EUH030 Can become highly flammable in use. It can become highly flammable during use.
EUH031 Contact with acids liberates toxic gas. Contact with acid releases toxic gases.
EUH032 Contact with acids liberates very toxic gas. Contact with acid to release highly toxic gases.
EUH044 Risk of explosion if heated under confinement. There is a danger of explosion when heated under closed conditions.
EUH059 Hazardous to the ozone layer. Hazard to the ozone layer.
EUH066 Repeated exposure may cause skin dryness or cracking. Repeated contact may cause dryness or cracking of the skin.
EUH070 Toxic by eye contact. Eye contact is toxic.
EUH071 Corrosive to the respiratory tract. Corrosive to the respiratory tract.
EUH201 Contains lead. Should not be used on surfaces liable to be chewed or sucked by children. Warning! Contains lead. Leaded. The surface should not be used and is easily chewed or sucked by children. caveat! Leaded.
EUH201A Warning! Contains lead. caveat! Leaded.
EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Instant adhesive. Danger. Bonds skin and eyes in seconds. Please keep this medicine out of the reach of children.
EUH203 Contains chromium (VI). May produce an allergic reaction. May cause an allergic reaction.
EUH204 Contains isocyanates. See information supplied by the manufacturer. Contains isocyanate. Refer to the information provided by the manufacturer.
EUH205 Contains epoxy constituents. See information supplied by the manufacturer. Contains epoxy resin. Refer to the information provided by the manufacturer.
EUH206 Warning! Do not use together with other products. May release dangerous gases (chlorine) . caveat! Do not use with other products. Harmful gases (chlorine) may be released.
EUH207 Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer. Comply with the safety instructions. caveat! Contains cadmium. Dangerous fumes formed during use. Information provided by the manufacturer. Follow the safety instructions.
EUH207-EG Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer. Comply with the safety instructions. caveat! Contains cadmium. Dangerous fumes formed during use. Information provided by the manufacturer. Follow the safety instructions.
EUH208 Contains (name of sensitising substance). May produce an allergic reaction. Contains (the name of the sensitizing substance). May cause an allergic reaction.
EUH208-EG Contains (name of sensitising substance). May produce an allergic reaction. Contains (the name of the sensitizing substance). May cause an allergic reaction.
EUH209 Can become highly flammable in use. Can become highly flammable in use.
EUH209a Can become highly flammable in use. Can become highly flammable in use.
EUH209b Can become flammable in use. Can become flammable in use.
EUH209A Can become flammable in use. Can become flammable in use.
EUH210 Safety data sheet available on request. Provide safety data sheet requirements.
EUH401 To avoid risks to human health and the environment, comply with the instructions for use. To avoid risks to human health and the environment, follow the instructions for use.
Precautionary statement
PRECAUTIONARY STATEMENTS

There are 116 separate and 33 combined caution statements
There are 116 individual and 33 combined Precautionary statements

Precautionary statement - ordinary Precautionary statements – General

P101 If medical advice is needed,have product container or label at hand. If you want medical advice, remember to bring your vials and labels
P102 Keep out of reach of children. Keep this medicine out of the reach of children.
P103 Read label before use. Read the label before use

Precautionary statement - prevention Precautionary statements – Prevention

P201 Obtain special instructions before use. Get special instructions before use.
P202 Do not handle until all safety precautions have been read and understood. Do not operate until you have read and understood all safety precautions.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Keep away from heat/sparks/open flames/hot surfaces. --No smoking.
P211 Do not spray on an open flame or other ignition source.  Do not spray on an open flame or other ignition source.
P220 Keep/Store away from clothing/…/combustible materials. Keep away from/store away from clothing/.../combustible materials.
P221 Take any precaution to avoid mixing with combustibles/… Take all precautions to avoid mixing with combustibles...
P222 Do not allow contact with air. Do not touch the air.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from any possibility of contact with water, as it may cause a flash fire if it reacts violently.
P230 Keep wetted with … Keep moist
P231 Handle under inert gas. Operate in an inert gas.
P232 Protect from moisture. Prevent moisture.
P233 Keep container tightly closed.  Keep the container closed.
P234 Keep only in original container. Only remain in the original container.
P235 Keep cool. Keep it cool.
P240 Ground/bond container and receiving equipment. Contact/connect containers and receiving equipment with the ground.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. Use explosion-proof electrical / ventilation / lighting / ... / equipment.
P242 Use only non-sparking tools. Use only non-sparking tools.
P243 Take precautionary measures against static discharge. Take precautions to prevent electrostatic discharge.
P244 Keep reduction valves free from grease and oil.  Keep the pressure reducing valve free of oil and grease.
P250 Do not subject to grinding/shock/…/friction. Do not be subject to grinding/shock/.../friction.
P251 Pressurized container: Do not pierce or burn, even after use. Pressure vessel: Do not puncture or incinerate, even after use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray. Do not breathe dust/fume/gas/mist/vapor/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid breathing dust/smoke/gas/mist/vapor/spray.
P262 Do not get in eyes, on skin, or on clothing. Do not touch your eyes, skin or clothing.
P263 Avoid contact during pregnancy/while nursing. Avoid contact during pregnancy/breastfeeding.
P264 Wash hands thoroughly after handling. Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling. Dispose of the skin thoroughly.
P270 Do not eat, drink or smoke when using this product. Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.  Use only outdoors or in a well ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace. Contaminated work clothes should not be taken out of the workplace.
P273 Avoid release to the environment. Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection. Wear protective gloves/protective clothing/eye protectors/face protectors.
P281 Use personal protective equipment as required. Use the personal protective equipment you need.
P282 Wear cold insulating gloves/face shield/eye protection. Wear cold gloves/mask/eye protection equipment.
P283 Wear fire/flame resistant/retardant clothing. Wear fire/flame retardant/flame resistant clothing.
P284 Wear respiratory protection.  Wear respiratory protection.
P285 In case of inadequate ventilation wear respiratory protection. Wear respiratory protection in case of insufficient ventilation.
P231+P232 Handle under inert gas. Protect from moisture. In an inert gas. Prevent moisture.
P235+P410 Keep cool. Protect from sunlight. keep cool. Avoid direct sunlight.

Precautionary statement - reaction Precautionary statements - Response

P301 IF SWALLOWED: If swallowed
P304 IF INHALED: If inhaled
P305 IF IN EYES: If you enter the eye
P306 IF ON CLOTHING: If on clothes
P307 IF exposed: If contact
P308 IF exposed or concerned: If contacted or involved
P309 IF exposed or if you feel unwell: If contact or if you feel unwell
P310 Immediately call a POISON CENTER or doctor/physician. Call a detoxification center or doctor/physician immediately.
P311 Call a POISON CENTER or doctor/physician. Call a detoxification center or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you feel unwell. Call a POISON CENTER or doctor/physician if you feel unwell.
P313 Get medical advice/attention. Get medical advice / medical advice
P314 Get medical advice/attention if you feel unwell. Get medical advice/medical care if you feel uncomfortable
P315 Get immediate medical advice/attention. Get medical advice / medical advice
P320 Specific treatment is urgent (see … on this label). Urgent specific treatment (see on this label).
P321 Specific treatment (see … on this label). Specific treatment (see on this label).
P322 Specific measures (see …on this label). Specific treatment (see on this label).
P330 Rinse mouth. gargle
P331 Do NOT induce vomiting.. Do not induce vomiting.
P332 IF SKIN irritation occurs: If skin irritation occurs:
P333 If skin irritation or rash occurs: If skin irritation or rash occurs:
P334 Immerse in cool water/wrap n wet bandages. Immerse in cold water/wet bandage wrap.
P335 Brush off loose particles from skin. Brush off loose particles from the skin.
P336 Thaw frosted parts with lukewarm water. Do not rub affected area. Thaw the frozen area and wash it off with warm water. Do not rub the affected area.
P337 If eye irritation persists: If eye irritation persists
P338 Remove contact lenses, if present and easy to do. Continue rinsing. If you wear invisible eyes and are easy to remove, remove the contact lenses and continue to rinse.
P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing. Transfer the patient to fresh air and keep at rest in a position suitable for breathing.
P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing difficulties occur, transfer the patient to fresh air and keep at rest in a position suitable for breathing.
P342 If experiencing respiratory symptoms: If respiratory symptoms occur:
P350 Gently wash with plenty of soap and water. Gently use plenty of soap and water
P351 Rinse cautiously with water for several minutes. Rinse carefully with water for a few minutes.
P352 Wash with plenty of soap and water. Wash with plenty of soap and water.
P353 Rinse skin with water/shower. Washing/shower washing skin
P360 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Rinse the contaminated clothing immediately, rinse the skin with plenty of water, and then take off your clothes.
P361 Remove/Take off immediately all contaminated clothing. Immediately remove/take off all contaminated clothing.
P362 Take off contaminated clothing and wash before reuse. Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse. The contaminated clothes can be reused after being washed.
P370 In case of fire: In the event of a fire:
P371 In case of major fire and large quantities: In the case of major fires and a large number of situations:
P372 Explosion risk in case of fire. There is a danger of a blast in the fire.
P373 DO NOT fight fire when fire reaches explosives. Do not save the fire when it is burned to explosives.
P374 Fight fire with normal precautions from a reasonable distance. Take normal safety precautions at the right distance to extinguish the fire.
P376 Stop leak if safe to do so. Oxidising gases (section 2.4) 1 If it is safe, stop the leak. Oxidizing gas.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Air leaks: Do not extinguish the fire unless the air leak can be safely stopped.
P378 Use … for extinction. Use... to extinguish the fire.
P380 Evacuate area. Evacuate the area.
P381 Eliminate all ignition sources if safe to do so. If safe, eliminate all sources of ignition.
P390 Absorb spillage to prevent material damage. Absorb spillage to prevent major damage.
P391 Collect spillage. Hazardous to the aquatic environment Collect spills that are hazardous to the water environment.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed: Call a poison control center or doctor/physician immediately.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. If swallowed: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If swallowing: gargle. Do not induce vomiting.
P302+P334 IF ON SKIN: Immerse in cool water/wrap in wet bandages. If the skin is contaminated: immerse in cold water / wrap with a wet bandage
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water. If on the skin: gently wash with plenty of soap and water
P302+P352 IF ON SKIN: wash with plenty of soap and water. Such as skin contact: Wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. If it gets on your skin (or hair): Remove / immediately remove all contaminated clothing. Wash/wash rinse the skin.
P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. If inhaled: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. If inhaled: Remove to fresh air, rest, and maintain a position suitable for breathing.
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If inhaled: If breathing is difficult, transfer the victim to fresh air and keep at rest in a position suitable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. If you come into contact with your eyes, carefully rinse your eyes with water for a few minutes.
P306+P360 IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. If it gets on your clothes: Immediately flush contaminated clothing and skin with plenty of water and then take off your clothes.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician. If contact: Call a detoxification center or doctor/physician.
P308+P313 IF exposed or concerned: Get medical advice/attention. If you are exposed or have doubts: seek medical advice/attention.
P309+P311 IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. If you are in contact or feel unwell: Call a POISON CENTER or doctor/physician.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention. If skin irritation occurs: Get medical advice/medical advice.
P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/medical advice.
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Brush off loose particles from the skin. Immerse in cold water / wrap it with a wet bandage
P337+P313 IF eye irritation persists: Get medical advice/attention. If eye irritation persists: Get medical advice/medical advice.
P342+P311 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. If respiratory symptoms occur: Call a POISON CENTER or doctor/physician.
P370+P376 in case of fire: Stop leak if safe to Do so. In the event of a fire, stop the leak in a safe situation.
P370+P378 In case of fire: Use … for extinction. In the event of a fire: use... to extinguish the fire.
P370+P380 in case of fire: Evacuate area. In the event of a fire: evacuate the site.
P370+P380+P375 in case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. In the event of a fire: evacuate the site. Fire from a distance because there is a danger of explosion.
P371+P380+P375 in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. In the case of major fires and large numbers; evacuation of the site takes into account the danger of explosion and should be fired from a distance.

Precautionary statement - storage Precautionary statements — Storage

P401 Store… storage
P402 Store in a dry place. Store in a dry place.
P403 Store in a well-ventilated place. Store in a well ventilated area.
P404 Store in a closed container. Store in a closed container.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse carefully with water for a few minutes. If you wear contact lenses and are easy to remove, remove the contact lenses. Continue to rinse.
P405 Store locked up. Lock and keep.
P406 Store in corrosive resistant/… container with a resistant inner liner. Store in a corrosion-resistant/resistant liner container.
P407 Maintain air gap between stacks/pallets. Maintain an air gap between the stack/pallet.
P410 Protect from sunlight. Prevent sun exposure.
P411 Store at temperatures not exceeding … oC/…oF. Store at temperatures not exceeding ...oC /...oF.
P412 Do not expose to temperatures exceeding 50 oC/ 122 oF. Do not expose to temperatures above 50 oC / 122 oF.
P413 Store bulk masses greater than … kg/…lbs at temperatures not exceeding … oC/…oF. When the store is more than ...kg/...lbs in bulk, the temperature should not exceed...oC/...oF.
P420 Store away from other materials. Keep away from other materials.
P422 Store contents under… The storage directory is under...
P402+P404 Store in a dry place. Store in a closed container. Store in a dry place. Store in a closed container.
P403+P233 Store in a well-ventilated place. Keep container tightly closed. Store in a well ventilated area. Keep the container closed.
P403+P235 Store in a well-ventilated place. Keep cool. Store in a well ventilated area. Keep it cool.
P410+P403 Protect from sunlight. Store in a well-ventilated place. Avoid direct sunlight. Store in a well ventilated area.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. Avoid direct sunlight. Do not expose to temperatures above 50 oC/122oF.
P411+P235 Store at temperatures not exceeding … oC/…oF. Keep cool Keep it cool.

Precautionary statement - handling Precautionary statements — Disposal

P501 Dispose of contents/container to..… Processing content/container.....
P502 Refer to manufacturer/supplier for information on recovery/recycling For recycling/recycling information, please refer to the manufacturer/supplier
Water hazard level
Water Hazard Class (WGK)

The German water hazard rating (wgk) is sometimes referred to as the German water hazard rating (wgk). This is usually included in Section 15 of the SDS. The German Federal Water Act requires that facilities that deal with hazardous substances in water must be constructed and operated in a manner that protects the water from pollution. To this end, the water hazard rating (WGK) of the substance or mixture must be determined, communicated and recorded.
According to the "Regulations on the Handling of Hazardous Substances to Water" of April 18, 2017(Verordnung_ber anlagen zum umgang mit wassergef_hrdendenden stoffen(AWSV))sort. There are three levels of water hazard(wgk):
German Water Hazard Class (WGK) sometimes is also called German Water Endangerment Class (WGK). This is often included in the section 15 of SDSs. German's Federal Water Act requires that facilities handling substances that are hazardous to waters must be built and operated in a way that water bodies are protected from pollutions. To this end, the Water Hazard Class (WGK) of a substance or mixture has to be determined, communicated and documented.
Classification is carried out on the basis of the Ordinance on facilities for handling substances that are hazardous to water (Verordnung über Anlagen zum Umgang mit wassergefährdenden Stoffen (AwSV)) of 18 April 2017. There are three water hazard classes (WGK):

1 low hazard to waters Low risk to water
2 hazard to waters Harmful to water
3 severe hazard to waters Serious damage to water
In addition, substances can be classified as harmless to water (NWG) or generally considered to be harmful to water (AWG).
Hazard category code
RISK CODES

The hazard category code is used to describe the danger of an object. It can indicate hazard category codes, safety precautions, and specific risks indicated. Commonly used to describe chemical reagents, dangerous goods. Chemically, used to describe the dangers of chemical agents. These risk phrase codes have the following meanings:
Risk Codes is used to describe the danger of an object. It can indicate the danger category code, safety precautions and specific risks indicated. It is widely used to describe chemical reagents and dangerous goods. Chemically, it is used to describe the danger of chemical reagents. . These risk phrase codes have the following meanings:

1
Explosive when dry.
Explosive when dry;
2
Risk of explosion by shock, friction, fire or other sources of ignition.
Explosion hazard due to impact, friction, fire or other sources of ignition;
3
Extreme risk of explosion by shock, friction, fire or other sources of ignition.
Risk of explosion due to impact, friction, fire or other sources of ignition;
4
Forms very sensitive explosive metallic compounds.
Producing extremely sensitive explosive metal compounds;
5
Heating may cause an explosion.
Heating may cause an explosion;
6
Explosive with or without contact with air.
Exploding with or without contact with air;
7
May cause fire.
May cause a fire;
8
Contact with combustible material may cause fire.
Contact with combustible materials may cause fire;
9
Explosive when mixed with combustible material.
Exploding when mixed with combustible materials;
10
Flammable.
flammable;
11
Highly flammable.
Highly flammable;
12
Extremely flammable.
Extremely flammable;
14
Reacts violently with water.
Reacts violently with water;
14/15
Reacts violently with water, liberating highly flammable gases.
Reacts violently with water, releasing extremely flammable gases;
15
Contact with water liberates extremely flammable gases.
Contact with water to release a very flammable gas;
15/29
Contact with water liberates toxic, highly flammable gas.
Contact with water to release toxic, extremely flammable gases;
16
Explosive when mixed with oxidizing substances.
Exploding when mixed with oxidizing substances;
17
Spontaneously flammable in air.
Easy to spontaneously ignite in the air;
18
In use, may form flammable/explosive vapour-air mixture.
A flammable/explosive vapor-air mixture may form during use;
19
May form explosive peroxides.
May generate explosive peroxides;
20
Harmful by inhalation.
Harmful by inhalation;
20/21
Harmful by inhalation and in contact with skin.
Inhalation and contact with the skin are harmful;
20/21/22
Harmful by inhalation, in contact with skin and if swallowed.
Inhalation, contact with skin and ingestion are harmful;
20/22
Harmful by inhalation and if swallowed.
Inhalation and ingestion are harmful;
21
Harmful in contact with skin.
Contact with the skin is harmful;
21/22
Harmful in contact with skin and if swallowed.
Contact with skin and swallowing is toxic;
22
Harmful if swallowed.
Ingestion is harmful;
23
Toxic by inhalation.
Harmful by inhalation;
23/24
Toxic by inhalation and in contact with skin.
Inhalation and contact with the skin are toxic;
23/24/25
Toxic by inhalation, in contact with skin and if swallowed.
Inhalation, contact with skin and ingestion are toxic;
23/25
Toxic by inhalation and if swallowed.
Inhalation and ingestion are toxic;
24
Toxic in contact with skin.
Toxic with skin;
24/25
Toxic in contact with skin and if swallowed.
Contact with skin and swallowing is toxic;
25
Toxic if swallowed.
Toxic if swallowed;
26
Very toxic by inhalation.
Inhalation is extremely toxic;
26/27
Very toxic by inhalation and in contact with skin.
Very toxic by inhalation and in contact with skin;
26/27/28
Very toxic by inhalation, in contact with skin and if swallowed.
Very toxic due to inhalation, contact with skin and ingestion;
26/28
Very toxic by inhalation and if swallowed.
Very toxic by inhalation and ingestion;
27
Very toxic in contact with skin.
Very toxic to contact with skin;
27/28
Very toxic in contact with skin and if swallowed.
Very toxic to skin contact and ingestion;
28
Very toxic if swallowed.
Very toxic by ingestion;
29
Contact with water liberates toxic gas.
Contact with water to release toxic gases;
30
Can become highly flammable in use.
Use becomes highly flammable;
31
Contact with acids liberates toxic gas.
Contact with acid to release toxic gases;
32
Contact with acids liberates very toxic gas.
Contact with acid to release extremely toxic gases;
33
Danger of cumulative effects.
Have a cumulative effect;
34
Causes burns.
Causing burns;
35
Causes severe burns.
Cause serious burns;
36
Irritating to eyes.
Irritating to the eyes;
36/37
Irritating to eyes and respiratory system.
Irritating to the eyes and respiratory system;
36/37/38
Irritating to eyes, respiratory system and skin.
Irritating to eyes, respiratory system and skin;
36/38
Irritating to eyes and skin.
Irritating to eyes and skin;
37
Irritating to respiratory system.
Stimulate the respiratory system;
37/38
Irritating to respiratory system and skin.
Stimulates the respiratory system and skin;
38
Irritating to skin.
Irritating to the skin;
39
Danger of very serious irreversible effects.
Risk of serious irreversible effects;
39/23
Toxic : danger of very serious irreversible effects through inhalation.
Toxic: the risk of extremely serious irreversible effects by inhalation;
39/23/24
Toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
Toxic: Risk of extremely serious irreversible effects through inhalation and contact with skin;
39/23/24/25
Toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
Toxic: Risk of extremely serious irreversible effects by inhalation, contact with skin and ingestion;
39/23/25
Toxic : danger of very serious irreversible effects through inhalation and if swallowed.
Toxic: risk of serious irreversible effects through inhalation and ingestion;
39/24
Toxic : danger of very serious irreversible effects in contact with skin.
Toxic: there is a serious risk of irreversible contact with the skin;
39/24/25
Toxic : danger of very serious irreversible effects in contact with skin and if swallowed.
Toxic: Risk of extremely serious irreversible effects when in contact with skin and if swallowed;
39/25
Toxic : danger of very serious irreversible effects if swallowed.
Toxic: the risk of serious irreversible effects when swallowed;
39/26
Very toxic : danger of very serious irreversible effects through inhalation.
Extremely highly toxic: there is a risk of serious irreversible effects by inhalation;
39/26/27
Very toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
Extremely highly toxic: a very serious irreversible risk of inhalation and contact with the skin;
39/26/27/28
Very toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
Extremely highly toxic: a serious irreversible risk of inhalation, contact with the skin and ingestion;
39/26/28
Very toxic : danger of very serious irreversible effects through inhalation and if swallowed.
Extremely highly toxic: a serious and irreversible risk of inhalation and ingestion;
39/27
Very toxic : danger of very serious irreversible effects in contact with skin.
Extremely highly toxic: there is a significant risk of irreversible contact with the skin;
39/27/28
Very toxic : danger of very serious irreversible effects in contact with skin and if swallowed.
Extremely highly toxic: there is a significant risk of irreversible contact with skin and swallowing;
39/28
Very toxic : danger of very serious irreversible effects if swallowed.
Extremely highly toxic: there is a risk of serious irreversible effects when swallowed;
40
Possible risks of irreversible effects.
There may be risks of irreversibility;
R40/20
Harmful : possible risk of irreversible effects through inhalation.
Harmful: The risk of irreversible effects by inhalation;
R40/20/21
Harmful : possible risk of irreversible effects through inhalation and in contact with skin.
Harmful: The risk of irreversible effects through inhalation and contact with the skin;
R40/20/21/22
Harmful : possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.
Harmful: may be irreversible by inhalation, contact with skin and if swallowed;
R40/20/22
Harmful : possible risk of irreversible effects through inhalation and if swallowed.
Harmful: may be irreversible by inhalation and ingestion;
R40/21
Harmful : possible risk of irreversible effects in contact with skin.
Harmful: exposure to skin may present an irreversible risk;
R40/21/22
Harmful : possible risk of irreversible effects in contact with skin and if swallowed.
Harmful: Risk of irreversible effects when in contact with skin and if swallowed;
R40/22
Harmful : possible risk of irreversible effects if swallowed
Harmful: the risk of irreversible effects when swallowed;
R41
Risk of serious damage to eyes.
Risk of serious damage to the eyes;
R42
May cause sensitization by inhalation.
Inhalation may cause allergies;
R42/43
May cause sensitization by inhalation and skin contact.
Inhalation and skin contact may cause allergies;
R43
May cause sensitization by skin contact.
Skin contact may cause allergies;
R44
Risk of explosion if heated under confinement.
Heating in a closed condition poses an explosion hazard;
R45
May cause cancer.
May cause cancer;
R46
May cause heritable genetic damage.
May cause irreversible genetic damage
R47
May cause birth defects.
May cause birth defects;
R48
Danger of serious damage to health by prolonged exposure.
Prolonged exposure has a serious risk of health damage;
R48/20
Harmful : danger of serious damage to health by prolonged exposure through inhalation.
Harmful: long-term exposure through inhalation has a serious risk of health damage;
R48/20/21
Harmful : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
Harmful: Risk of serious damage to health through inhalation and prolonged contact with the skin;
R48/20/21/22
Harmful : danger of serious damage to health by prolonged exposure through inh.,in contact with skin and if swallowed
Harmful: Prolonged exposure to inhalation, skin and if swallowed is a serious health hazard;
R48/20/22
Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
Harmful: Prolonged exposure to inhalation and ingestion poses a risk of serious health hazards;
R48/21
Harmful : danger of serious damage to health by prolonged exposure in contact with skin.
Harmful: long-term exposure to the skin poses a serious risk of health damage;
R48/21/22
Harmful : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
Harmful: long-term exposure to skin and swallowing poses a risk of serious health hazards;
R48/22
Harmful : danger of serious damage to health by prolonged exposure if swallowed.
Harmful: swallowing long-term exposure has a serious risk of health damage;
R48/23
Toxic : danger of serious damage to health by prolonged exposure through inhalation.
Toxic: long-term exposure through inhalation has a serious risk of health damage;
R48/23/24
Toxic : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
Toxic: Risk of serious damage to health through inhalation and prolonged contact with the skin;
R48/23/24/25
Toxic : danger of serious damage to health by prolonged exposure through inh.,in contact with skin and if swallowed
Toxic: Risk of serious damage to health through prolonged exposure through inhalation, skin and if swallowed;
R48/23/25
Toxic : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
Toxic: long-term exposure through inhalation and ingestion poses a risk of serious health hazards;
R48/24
Toxic : danger of serious damage to health by prolonged exposure in contact with skin.
Toxic: long-term exposure to the skin poses a serious risk of health damage;
R48/24/25
Toxic : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
Toxic: long-term exposure to the skin and if swallowed, posing a serious risk to health;
R48/25
Toxic : danger of serious damage to health by prolonged exposure if swallowed.
Toxic: swallowing long-term exposure has a serious risk of health damage;
R49
May cause cancer by inhalation.
Inhalation may cause cancer;
R50
Very toxic to aquatic organisms.
Very toxic to aquatic organisms;
R50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment;
R51
Toxic to aquatic organisms.
Toxic to aquatic life;
R51/53
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment;
R52
Harmful to aquatic organisms.
Harmful to aquatic life;
R52/53
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment;
R53
May cause long-term adverse effects in aquatic environment.
May cause long-term adverse effects in the aquatic environment;
R54
Toxic to flora.
Toxic to flora;
R55
Toxic to fauna.
Toxic to fauna;
R56
Toxic to soil organisms.
Toxic to organisms in the soil;
R57
Toxic to bees.
Toxic to bees;
R58
May cause long-term adverse effects in the environment.
May cause long-term adverse effects in the environment;
R59
Dangerous for the ozon layer.
Harmful to the ozone layer;
R60
May impair fertility.
May damage fertility;
R61
May cause harm to the unborn child.
May cause harm to unborn babies;
R62
Possible risk of impaired fertility.
May be at risk of damaging fertility;
R63
Possible risk of harm to the unborn child.
May be at risk of harming an unborn baby;
R64
May cause harm to breastfed babies.
May cause harm to breast-feeding babies;
R65
Harmfull may cause lung damage if swallowed
If swallowed, it may cause lung damage
Security code
SECURITY CODES

EC safety codes are commonly used in chemical data sheets in many countries around the world. The meaning of these codes is as follows:

S1 Keep closed.
S2 Store out of reach of children.
S3 Store in a cool place.
S4 Store away from residential areas.
S5 Save in... (the name of a liquid).
S6 Store in an atmosphere (the name of an inert gas).
S7 Keep the container tightly closed.
S8 Keep the container dry.
S9 Keep the container in a well ventilated place.
S12 Do not seal the container.
S13 Keep away from food, drinks and animal feed.
S14 Stay away from ... (list incompatible substances).
S15 Keep away from heat.
S16 Keep away from fire.
S17 Keep away from combustible materials.
S18 Be careful when handling and opening containers.
S20 Do not eat at the same time when using.
S21 Do not smoke while using.
S22 Do not inhale dust.
S23 Do not breathe steam.
S24 Avoid contact with the skin.
S25 Avoid contact with your eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27 Remove all contaminated clothing immediately.
S28 Immediately after contact with the skin, wash with plenty of soap.
S29 Do not pour the residue into the drain.
S30 Never add water to this product.
S33 Take protective measures to prevent static electricity from occurring.
S35 The residue of this material and its container must be disposed of in a safe manner.
S36 Wear suitable protective clothing.
S37 Use suitable protective gloves.
S38 Wear a suitable breathing apparatus in a poorly ventilated area.
S39 Wear eye/face protection.
S40 Clean the ground and objects contaminated with the substance and use (the appropriate cleaning material name).
S41 Do not breathe in the event of a fire and/or explosion.
S42 Wear suitable breathing apparatus when extinguishing fires.
S43 Use ... (a suitable fire extinguishing device name) for fire fighting.
S45 If you have an accident or feel unwell, go to the doctor for help (preferably take the product container label).
S46 In case of accidental swallowing, seek medical advice (show product containers or labels).
S47 Keep the temperature not exceeding...
S48 Keep it moist (the name of a substance) with...
S49 Can only be saved in the original container.
S50 Don't mix with...
S51 Use only in well ventilated areas.
S52 It is not recommended for use in large areas of interior space.
S53 Avoid exposure - read the special instructions before use.
S56 Discard the residue and packaging container at a specially designated waste collection point.
S57 Use a suitable container to avoid environmental contamination.
S59 Refer to the information provided by the manufacturer and supplier for recycling.
S60 The residue and container of this material must be disposed of as hazardous waste.
S61 Avoid discharge to the environment. Refer to the specific instructions / safety data sheet.
S62 If swallowed, do not induce vomiting; seek medical attention immediately and present the product container or label.
S1/2 Keep sealed and keep away from children.
S24/25 Prevent skin and eye contact.
S36/37 Wear suitable protective clothing and gloves.
S36/37/39 Wear suitable protective clothing, gloves, and safety glasses or a face shield.
S37/39 Use suitable gloves and safety glasses or a face shield.
Dangerous goods sign and logo

Many countries require dangerous symbolic signs on the appearance of the product's containers. These symbols are expressed as follows:

E E : Explosive Explosives Explosive Explosives
O O : Oxidizing agent Oxidant Oxidizing agent Oxidant
F++ F++ : Extremely flammable Extremely flammable Extremely flammable Extremely flammable
F+ F+ : Highly flammable Highly flammable Highly flammable Highly flammable
F F : Flammable Flammable Flammable Flammable
T+ T+ : Very toxic Drug Very toxic Drug
T T : Toxic poisonous Toxic poisonous
Xn Xn : Harmful harmful Harmful harmful
Xi Xi : Irritant Stimulant Irritant Stimulant
C C : Corrosive Corrosive Corrosive Corrosive
N N : Dangerous for the environment Harmful to the environment Dangerous for the environment Harmful to the environment
Pictogram symbol and dangerous goods sign
PICTOGRAMS AND HAZARD CODES

The most obvious change in the current EU system is the pictogram (formerly known as the hazard symbol). Although most of the GHS pictograms
Compared to the current EU system the most noticeable change are the pictograms (formerly: hazard symbols).

Note: Although most GHS pictograms are the same as in the old system, the pictograms GHS 04, GHS 07 and GHS 08 are brand new. The GHS system is based on 16 physics, 10 health and 3 environmental hazard categories and includes the following communication elements:
Note: While the most of the GHS pictograms have an equivalent in the old system, the pictograms GHS 04, GHS 07 and GHS 08 are completely new. The GHS System is built on 16 physical, 10 health and 3 environmental hazard classes and comprises the following communication elements:

description(Description) Pictogram symbol(Pictogram) Hazard categories and hazard categories Hazard class and hazard category
GHS01
Detonated bomb
(Exploding Bomb)
GHS01 Detonated bomb(Exploding Bomb) Unstable explosive Unstable explosives
Explosives category 1.1, 1.2, 1.3, 1.4 Explosives of Divisions 1.1, 1.2, 1.3, 1.4
Self-reactive substances and mixtures, categories A, B Self reactive substances and mixtures, Types A,B
Organic peroxides, categories A, B Organic peroxides, Types A,B
GHS02
flame
(Flame)
GHS02 flame(Flame) Flammable gas category 1 Flammable gases, category 1
Flammable sol, class 1, 2 Flammable aerosols, categories 1,2
Flammable liquid, category 1, 2, 3 Flammable liquids, categories 1,2,3
Flammable solids, category 1, 2 Flammable solids, categories 1,2
Self-reactive substances and mixtures, type B, C, D, E, F Self-reactive substances and mixtures, Types B,C,D,E,F
Spontaneous combustion liquid category 1 Pyrophoric liquids, category 1
Spontaneous combustion solid category 1 Pyrophoric solids, category 1
Self-heating substances and mixtures, category 1,2 Self-heating substances and mixtures,
Substances and mixtures that come into contact with water, releasing flammable gases Category 1, 2, 3 Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, category B, C, D, E, F Organic peroxides, Types B,C,D,E,F
GHS03
Flame surrounded by rings
(Flame Over Circle)
GHS03 Flame surrounded by rings(Flame Over Circle) Oxidizing gas, class 1 Oxidizing gases, category 1
Oxidizing liquid, category 1, 2, 3 Oxidizing liquids, categories 1,2,3
GHS04
Gas cylinder
(Gas Cylinder)
GHS04 Gas cylinder(Gas Cylinder) Gas under pressure: Gases under pressure:
compressed gas Compressed gases
Liquefied gas Liquefied gases
Freezing liquefied gas Refrigerated Liquefied gases
Dissolved gas Dissolved gases
GHS05
corrosion
(Corrosion)
GHS05 corrosion(Corrosion) Corrosion metal, category 1 Corrosive to metals, category 1
Corrosive skin, category 1A, 1B, 1C Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1 Serious eye damage, category 1
GHS06
Flag
(Skull and Crossbones)
GHS06 Flag(Skull and Crossbones) Acute toxicity (oral, skin contact, inhalation), category 1, 2, 3 Acute toxicity (oral, dermal, inhalation), categories 1,2,3
GHS07
Exclamation mark
(Exclamation Mark)
GHS07 Exclamation mark(Exclamation Mark) Acute toxicity (oral, skin contact, inhalation), category 4 Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2 Skin irritation, category 2
Eye irritation, category 2 Eye irritation, category 2
Skin allergies, category 1 Skin sensitisation, category 1
Specific target organ toxicity - one contact, category 3 Specific Target Organ Toxicity – Single exposure, category 3
GHS08
Health hazard
(Health Hazard)
GHS08 Health hazard(Health Hazard) Respiratory allergy, category 1 Respiratory sensitization, category 1
Germ cell mutation, category 1A, 1B, 2 Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, Category 1A, 1B, 2 Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, category 1A, 1B, 2 Reproductive toxicity, categories 1A,1B,2
Specific target organ toxicity - single exposure, category 1, 2 Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific target organ toxicity - repeated exposure, categories 1, 2 Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Inhalation hazard, category 1 Aspiration Hazard, category 1
GHS09
surroundings
(Environment)
GHS09 surroundings(Environment) Harm to the water environment Hazardous to the aquatic environment
Acute hazard, category 1 Acute hazard, category1
Chronic hazard, category 1, 2 Chronic hazard, categories 1,2