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二(4,4,5,5-四甲基-1,3,2-二氧杂戊硼烷-2-基)甲烷 | 78782-17-9
二(4,4,5,5-四甲基-1,3,2-二氧杂戊硼烷-2-基)甲烷 | 78782-17-9
中文名称:
二(4,4,5,5-四甲基-1,3,2-二氧杂戊硼烷-2-基)甲烷
英文名称:
Bis[(pinacolato)boryl]methane
CAS No.:
78782-17-9
分子式:
C1 3 H2 6 B2 O4
分子量:
267.965144634247
名称和标识符
MDL
MFCD27977747
InChIKey
MQYZGGWWHUGYDR-UHFFFAOYSA-N
Inchi
1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3
SMILES
O1C(C)(C)C(C)(C)OB1CB1OC(C)(C)C(C)(C)O1
别名信息
- 中文别名 -
双[(频哪醇)硼基]甲烷
2,2'-亚甲基双(4,4,5,5-四甲基-1,3,2-二氧杂戊硼烷)
Bis[(pinacolato)boryl]methane 双[(频哪醇)硼基]甲烷
二[(频哪醇)硼基]甲烷
二(4,4,5,5-四甲基-1,3,2-二氧杂戊硼烷-2-基)甲烷
- 英文别名 -
Bis[(pinacolato)boryl]methane
Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methane
4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane
2,2′-Methylenebis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]
2,2'-Methylenebis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
bis[(pinacolato)boryl]methane
2,2′-Methylenebis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane] (ACI)
4,4,5,5-Tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane
Bis((pinacolato)boryl)methane
Methylenedi(boronic Acid Pinacol Ester)
Methylenedi(boronic Acid Pinacol Ester)
AMY1128
AMY1128
SY040252
SY040252
DS-11521
DS-11521
CS-0153823
CS-0153823
2,2'-Methylenebis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]
2,2'-Methylenebis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]
FT-0663384
FT-0663384
1,3,2-Dioxaborolane, 2,2'-methylenebis[4,4,5,5-tetramethyl-
1,3,2-Dioxaborolane, 2,2'-methylenebis[4,4,5,5-tetramethyl-
EN300-214736
EN300-214736
H10252
H10252
AKOS027324523
AKOS027324523
SCHEMBL10001281
SCHEMBL10001281
A914795
A914795
4,4,5,5-tetramethyl-2-[(tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane
4,4,5,5-tetramethyl-2-[(tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane
DTXSID80462021
DTXSID80462021
78782-17-9
78782-17-9
MFCD27977747
MFCD27977747
B4103
B4103
物化性质
实验特性
LogP
2.71000
PSA
36.92000
沸点
272.0±23.0 °C at 760 mmHg
熔点
51.0 to 55.0 deg-C
闪点
华氏:>230 °F 摄氏:>110 °C
颜色与性状
No data available
计算特性
精确分子量
268.20200
氢键供体数量
0
氢键受体数量
4
可旋转化学键数量
2
同位素质量
268.2017196g/mol
重原子数量
19
复杂度
300
同位素原子数量
0
确定原子立构中心数量
0
不确定原子立构中心数量
0
确定化学键立构中心数量
0
不确定化学键立构中心数量
0
共价键单元数量
1
拓扑分子极性表面积
36.9Ų
相关文献
1.
Recent developments in the asymmetric synthesis and functionalization of symmetrical and unsymmetrical gem-diborylalkanes
Swagata Paul,Kanak Kanti Das,Debasis Aich,Samir Manna,Santanu Panda Org. Chem. Front. 2022 9 838
2.
Advances in transition metal-free deborylative transformations of gem-diborylalkanes
Woohyun Jo,Jun Hee Lee,Seung Hwan Cho Chem. Commun. 2021 57 4346
3.
Palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane: synthesis of homoallylic boronic esters
Chunsheng Li,Meng Li,Jianxiao Li,Wanqing Wu,Huanfeng Jiang Chem. Commun. 2018 54 66
4.
Base-promoted, deborylative secondary alkylation of N-heteroaromatic N-oxides with internal gem-bis[(pinacolato)boryl]alkanes: a facile derivatization of 2,2′-bipyridyl analogues
Chiwon Hwang,Woohyun Jo,Seung Hwan Cho Chem. Commun. 2017 53 7573
5.
Restoration of catalytic activity by the preservation of ligand structure: Cu-catalysed asymmetric conjugate addition with 1,1-diborylmethane
Changhee Kim,Byeongdo Roh,Hong Geun Lee Chem. Sci. 2021 12 3668
6.
Repurposing pinacol esters of boronic acids for tuning viscoelastic properties of glucose-responsive polymer hydrogels: effects on insulin release kinetics
Akbar Ali,Shaista Nouseen,Saroj Saroj,Meenakshi Shegane,Priyankar Majumder,Aarti Puri,Tatini Rakshit,Debasish Manna,Suchetan Pal J. Mater. Chem. B 2022 10 7591
7.
Cooperative bimetallic catalysis in asymmetric allylic substitution
Jingke Fu,Xiaohong Huo,Bowen Li,Wanbin Zhang Org. Biomol. Chem. 2017 15 9747
8.
α-Hydroxy boron-enabled regioselective access to bifunctional halo-boryl alicyclic ethers and α-halo borons
Lucia Wang,Shengjia Lin,Yawei Zhu,Daniel Ferrante,Timaf Ishak,Yuki Baba,Abhishek Sharma Chem. Commun. 2021 57 4564
9.
Installing the “magic methyl” – C–H methylation in synthesis
Daniya Aynetdinova,Mia C. Callens,Harry B. Hicks,Charmaine Y. X. Poh,Benjamin D. A. Shennan,Alistair M. Boyd,Zhong Hui Lim,Jamie A. Leitch,Darren J. Dixon Chem. Soc. Rev. 2021 50 5517
10.
Catalytic allylic functionalization via π-allyl palladium chemistry
Rodney A. Fernandes,Jothi L. Nallasivam Org. Biomol. Chem. 2019 17 8647
二(4,4,5,5-四甲基-1,3,2-二氧杂戊硼烷-2-基)甲烷推荐生产厂家
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