甲酰胺 | 75-12-7
中文名称:
甲酰胺
英文名称:
Formamide
CAS No.:
75-12-7
分子式:
CH3 NO
分子量:
45.0406
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:甲酰胺结构式
名称和标识符
MDL
MFCD00007941
InChIKey
ZHNUHDYFZUAESO-UHFFFAOYSA-N
Inchi
1S/CH3NO/c2-1-3/h1H,(H2,2,3)
SMILES
O=C([H])N([H])[H]
BRN
505995
别名信息
- 中文别名 -
甲酰胺
氨基甲醛
甲醯胺
去离子
Formamide 甲酰胺
表面湿润张力测试剂NO.58.0
二类残留溶剂-甲酰胺
甲酰胺, 用于分析
甲酰胺,AR
甲酰胺,GR
甲酰胺,HPLC
毛细管电泳级甲酰胺
去离子甲酰胺
水合肼
甲酰胺,Formamide,AR
甲酰胺,Formamide,CP
甲酰胺,Formamide,极谱记录仪和非水滴定专用
甲酰胺用途
郑州甲酰胺
C1 酰胺
氯丙烯
- 英文别名 -
Formamide
Formamide Methanamide
Formamide, Molecular Biology Grade Methanamide, Molecular Biology Grade
Formamide, MB Grade (1.12017)
FORMAMIDE HDPE
FORMAMIDE, MOLECULAR BIOLOGY GRADE
FORMAMIDE, DEIONIZED
AMide C1
formamidic acid
ForMic acid aMide
formic-d acid,potassium salt
formimidic acid
Formimidsaeure
ForMylaMide
Hydroxyformaldimin
Kalium-d-formiat
potassium deuteroformate
Potassium formate-d
Formamide in dimethyl sulfoxide
Carbamaldehyde
Methanamide
NSC 748
甲酰胺
Formic acid, amide
formamid
Methanoic acid, amide
Amid kyseliny mravenci
Amid kyseliny mravenci [Czech]
Formic amide
HCONH2
Carbamaldehyde, Methanamide
ZHNUHDYFZUAESO-UHFFFAOYSA-N
4781T907ZS
DSSTox_CID_5337
DSSTox_RID_77755
DSSTox_GSID_25337
FORMAMIDE, ULTRA PURE
Formamide, 99.5+%, extra pure
Formamide, 99.5%, for analysis
Formamide, 99+%, fo
物化性质
实验特性
LogP
0.43770
PSA
43.09000
Merck
4237
折射率
n20/D 1.447(lit.) n20/D 1.447
水溶性
miscible
沸点
210 °C(lit.)
熔点
2-3 °C (lit.)
蒸气压
0.08 mmHg ( 20 °C) 30 mmHg ( 129 °C)
闪点
华氏:347 °F 摄氏:175 °C
溶解度
H2O: 10 M at 20 °C, clear, colorless
颜色与性状
无色透明的黏稠液体,略有氨味,吸湿。
PH值
8-10 (200g/l, H2O, 20℃)
溶解性
能与水、醇、乙二醇、丙酮、乙酸、二烷、甘油、苯酚等混溶。但几乎不溶于脂肪烃、芳香烃、醚、氯代烃、氯苯、硝基苯等。
敏感性
Hygroscopic
密度
1.134 g/mL at 25 °C(lit.)
计算特性
精确分子量
45.02150
氢键供体数量
1
氢键受体数量
1
可旋转化学键数量
0
同位素质量
45.021464
重原子数量
3
复杂度
12.3
同位素原子数量
0
确定原子立构中心数量
0
不确定原子立构中心数量
0
确定化学键立构中心数量
0
不确定化学键立构中心数量
0
共价键单元数量
1
疏水参数计算参考值(XlogP)
-0.8
互变异构体数量
2
表面电荷
0
拓扑分子极性表面积
43.1
海关数据
海关编码
2924199090
海关数据
中国海关编码:
2924199090
概述:
2924199090. 其他无环酰胺(包括无环氨基甲酸酯)(包括其衍生物及盐). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 包装
Summary:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
相关文献
1.
Photoinduced carbamoylation reactions: unlocking new reactivities towards amide synthesis
Bianca T. Matsuo,Pedro H. R. Oliveira,Emanuele F. Pissinati,Kimberly B. Vega,Iva S. de Jesus,Jose Tiago M. Correia,Márcio Paixao Chem. Commun. 2022 58 8322
2.
Cu-Catalyzed carbamoylation versus amination of quinoline N-oxide with formamides
Yan Zhang,Shiwei Zhang,Guangxing Xu,Min Li,Chunlei Tang,Weizheng Fan Org. Biomol. Chem. 2019 17 309
3.
Recent advances in transition metal-catalyzed reactions of carbamoyl chlorides
Mohini Shrestha,Xianqing Wu,Wenyi Huang,Jingping Qu,Yifeng Chen Org. Chem. Front. 2021 8 4024
4.
Oxamic acids: useful precursors of carbamoyl radicals
Ikechukwu Martin Ogbu,Gülbin Kurtay,Frédéric Robert,Yannick Landais Chem. Commun. 2022 58 7593
5.
An efficient approach for the synthesis of new (±)-coixspirolactams
Vinicius R. Nascimento,Melissa L. S. Suenaga,Leandro H. Andrade Org. Biomol. Chem. 2020 18 5458
6.
Photochemical generation of acyl and carbamoyl radicals using a nucleophilic organic catalyst: applications and mechanism thereof
Eduardo de Pedro Beato,Daniele Mazzarella,Matteo Balletti,Paolo Melchiorre Chem. Sci. 2020 11 6312
7.
Iodine-DMSO mediated conversion of N-arylcyanothioformamides to N-arylcyanoformamides and the unexpected formation of 2-cyanobenzothiazoles
Ziad Moussa,Zaher M. A. Judeh,Ahmed Alzamly,Saleh A. Ahmed,Harbi Tomah Al-Masri,Bassam Al-Hindawi,Faisal Rasool,Sara Saada RSC Adv. 2022 12 6133
8.
Carbamoyl anion-initiated cascade reaction for stereoselective synthesis of substituted α-hydroxy-β-amino amides
Chao-Yang Lin,Peng-Ju Ma,Zhao Sun,Chong-Dao Lu,Yan-Jun Xu Chem. Commun. 2016 52 912
9.
Photogenerated acyl/alkoxycarbonyl/carbamoyl radicals for sustainable synthesis
Carlotta Raviola,Stefano Protti,Davide Ravelli,Maurizio Fagnoni Green Chem. 2019 21 748
10.
Polymorphs and solvates of felodipine: analysis of crystal structures and thermodynamic aspects of sublimation and solubility processes
German L. Perlovich,Svetlana V. Blokhina,Nikolay G. Manin,Tatyana V. Volkova,Valery V. Tkachev CrystEngComm 2012 14 8577
参考资料
Reaxys RN
505995
Beilstein
505995
960化工网为您提供甲酰胺专业化合物百科信息,包括中文名,英文名,分子式,分子量,以及该化合物的CasNo.:75-12-7,和相关理化性质;并提供了优质生产厂家信息包括厂家名称和联系方式等