三乙基磷 | 554-70-1
中文名称:
三乙基磷
英文名称:
Triethylphosphine Solution (1.0 M in toluene)
CAS No.:
554-70-1
分子式:
C6 H1 5 P
分子量:
118.1571
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:三乙基磷结构式
简介
三乙基磷(Triethylphosphine)
名称和标识符
MDL
MFCD00009256
InChIKey
RXJKFRMDXUJTEX-UHFFFAOYSA-N RXJKFRMDXUJTEX-UHFFFAOYSA-N
Inchi
InChI=1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3
SMILES
CCP(CC)CC
别名信息
- 中文别名 -
三乙基磷
三乙基膦
三乙基瞵
三乙膦
三乙基磷化氫
- 英文别名 -
Triethylphosphine
triethyl phosphine vial with 10 G
Triethylphosphine solution
Triethylphosphineredistilled
TriethylphosphineSureSealbottlecolorlessliq
Triethylphosphineinethanol
Triethylphosphin
triethoxyphosphine
triethylphosphane
PEt3
Triethylphosphorous solution
HishicolinP 2
Triethylphosphorus
物化性质
实验特性
LogP
2.52800
PSA
13.59000
Merck
14,9675
折射率
1.456
水溶性
Insoluble in water.
沸点
127-128 ºC
熔点
-88°C
闪点
华氏:-4 °F 摄氏:-20 °C
浓度
1.0 M in 2-methyltetrahydrofuran
颜色与性状
无色有刺激气味的液体
溶解性
不易和水混合
敏感性
Air & Moisture Sensitive
密度
0.843 g/mL
计算特性
精确分子量
118.09100
氢键供体数量
0
氢键受体数量
0
可旋转化学键数量
3
重原子数量
7
复杂度
25.7
同位素原子数量
0
确定原子立构中心数量
0
不确定原子立构中心数量
0
确定化学键立构中心数量
0
不确定化学键立构中心数量
0
共价键单元数量
1
疏水参数计算参考值(XlogP)
1
互变异构体数量
无
表面电荷
0
相关文献
1.
Bis(phosphine)bis(tellurocarboxylato)-palladium(II) and -platinum(II) complexes: synthesis and crystal structure
Shinzi Kato,Osamu Niyomura,Yasuyuki Kawahara,Takahiro Kanda J. Chem. Soc. Dalton Trans. 1999 1677
2.
C–F Bond activation at Ni(0) and simple reactions of square planar Ni(ii) fluoride complexes
Suzanne Burling,Paul I. P. Elliott,Naser A. Jasim,Richard J. Lindup,Jennifer McKenna,Robin N. Perutz,Stephen J. Archibald,Adrian C. Whitwood Dalton Trans. 2005 3686
3.
Steric influence of salicylaldehyde-based Schiff base ligands on the formation of trans-[Re(PR3)2(Schiff base)]+ complexes
Jakob E. Baumeister,Andrew W. Mitchell,Steven P. Kelley,Charles L. Barnes,Silvia S. Jurisson Dalton Trans. 2019 48 12943
4.
Steric influence of salicylaldehyde-based Schiff base ligands on the formation of trans-[Re(PR3)2(Schiff base)]+ complexes
Jakob E. Baumeister,Andrew W. Mitchell,Steven P. Kelley,Charles L. Barnes,Silvia S. Jurisson Dalton Trans. 2019 48 12943
5.
The carbonylation of methanol catalysed by [RhI(CO)(PEt3)2]; crystal and molecular structure of [RhMeI2(CO)(PEt3)2]??
Joanne Rankin,Attila C. Benyei,Andrew D. Poole,David J. Cole-Hamilton J. Chem. Soc. Dalton Trans. 1999 3771
6.
Synthesis of a rhodium(i) germyl complex: a useful tool for C–H and C–F bond activation reactions
Theresia Ahrens,Mike Ahrens,Thomas Braun,Beatrice Braun,Roy Herrmann Dalton Trans. 2016 45 4716
7.
(Ar–CO–CC)(PEt3)Au and (Ar–CC)(PEt3)Au complexes bearing pyrenyl and ferrocenyl groups: synthesis, structure, and luminescence properties
Marta G?odek,Anna Makal,Piotr Paluch,Mariola Kadzio?ka-Gawe?,Yasuhiro Kobayashi,Janusz Zakrzewski,Damian Pla?uk Dalton Trans. 2018 47 6702
8.
Complexes trans-Pt(BODIPY)X(PEt3)2: excitation energy-dependent fluorescence and phosphorescence emissions, oxygen sensing and photocatalysis
Peter Irmler,Rainer F. Winter Dalton Trans. 2016 45 10420
9.
Phosphine-ligated induced formation of thallium(i) “full” Pt3TlPt3 sandwich versus
“open-face” TlPt3 sandwich with triangular Pt3(μ2-CO)3(PR3)3 units: synthesis and structural/spectroscopic analysis of triphenylphosphine [(μ3-Tl)Pt3(μ2-CO)3(PPh3)3]+ and its (μ3-AuPPh3)Pt3 analogue
Namal de Silva,Charles G. Fry,Lawrence F. Dahl “open-face” TlPt3 sandwich with triangular Pt3(μ2-CO)3(PR3)3 units: synthesis and structural/spectroscopic analysis of triphenylphosphine [(μ3-Tl)Pt3(μ2-CO)3(PPh3)3]+ and its (μ3-AuPPh3)Pt3 analogue. Namal de Silva Charles G. Fry Lawrence F. Dahl Dalton Trans. 2006 1051
10.
Competing C–H and C–F bond activation reactions of a fluorinated olefin at Rh: a fluorido vinylidene complex as an intermediate in an unprecedented dehydrofluorination step
Maria Talavera,Thomas Braun Chem. Sci. 2022 13 1130
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