叠氮磷酸二苯酯 | 26386-88-9
中文名称:
叠氮磷酸二苯酯
英文名称:
{azido(phenoxy)phosphoryloxy}benzene
CAS No.:
26386-88-9
分子式:
C1 2 H1 0 N3 O3 P
分子量:
275.2
名称和标识符
MDL
MFCD00001987
InChIKey
SORGEQQSQGNZFI-UHFFFAOYSA-N
Inchi
InChI=1S/C12H10N3O3P/c13-14-15-19(16,17-11-7-3-1-4-8-11)18-12-9-5-2-6-10-12/h1-10H
SMILES
C1=CC=C(C=C1)OP(=O)(N=[N+]=[N-])OC2=CC=CC=C2
BRN
2058967
别名信息
- 中文别名 -
叠氮磷酸二苯酯
二甲基磷酸基叠氮化物
二苯基磷酰叠氮化物
叠氮化二苯基磷酰
叠氮化磷酸二苯酯
二甲基磷酸叠氮化物
叠氮磷酸二苯酯(DPPA)
Diphenylphosphoryl Azide 叠氮磷酸二苯酯
叠氮磷酸二苯酯 (DPPA)
叠氮磷酸二苯酯DPPA
叠氮膦酸二苯酯
叠氮基磷酸二苯酯
叠氮磷酸二苯酯厂家|生产厂家
- 英文别名 -
diphenyl azidophosphate
Diphenylphosphoryl azide
diphenyl phosphorazidate
DIPHENYLPHOSPHORYL AZIDE, POLYMER-BOUND
DIPHENYLPHOSPHORIC AZIDE
DIPHENYLPHOSPHONIC AZIDE
DPPA POLYMER-BOUND
DPPA
Diphenyl phosphoryl azide (DPPA)
{[Azido(phenoxy)phosphoryl]oxy}benzene
diphenyl phosphoroazidate
Diphenyl phosphoryl
diphenylphophoryl azide
Diphenylphoshoryl azide
diphenylphosphoric acid amide
diphenylphosphoric acid azide
Diphenyphosphoryl azide
phosphorazidic acid diphenyl ester
Phosphoric acid diphenyl ester azide
PS-DPPA
Diphenylphosphonoazide
DIPHENYLPHOSPHORYL AZIDE [MI]
EN300-55951
MFCD00001987
(azido(phenoxy)phosphoryl)oxybenzene
BCP04388
D1672
AKOS009159231
diphenyl phosphoryl azide (dppa)
(PhO)2P(O)N3
diphenoxyphosphoryl azide
NS00051263
diphenylphosphoric azide
{[azido(phenoxy)phosphoryl]oxy}benzene
SCHEMBL80417
AS-15330
DTXSID10949274
Diphenylphosphorazidate
AM86815
DPPA
Diphenylphosphoryl azide
J-670021
DIPHENYL PHOSPHORAZIDE
D89907
Diphenyl phosphonyl azide
(PhO)2PON3
Q-201011
AZIDODIPHENOXYOXOPHOSPHORANE
diphenoxyphosphinylazide
Diphenyl azidophosphate
Diphenyl azidophosphonate
26386-88-9
(PhO)2 PON3
AZIDOPHOSPHORIC ACID DIPHENYL ESTER
F0001-0870
Phosphorazidic acid, diphenyl ester
UNII-GXM91165AV
GXM91165AV
EINECS 247-644-0
[azido(phenoxy)phosphoryl]oxybenzene
Diphenylphosphonic azide
FT-0601125
o,o-diphenylphosphoryl azide
diphenylphosphoroazidate
Diphenylphosphonic azide,98%
{azido(phenoxy)phosphoryloxy}benzene
物化性质
实验特性
LogP
4.01556
PSA
95.09000
折射率
n20/D 1.551(lit.)
水溶性
不溶
沸点
157 °C/0.17 mmHg(lit.)
熔点
No data available
蒸气压
No data available
闪点
华氏:233.6 °F 摄氏:112 °C
溶解度
Immiscible with water.
颜色与性状
未确定
稳定性
Stable. Incompatible with acids, strong oxidizing agents.
溶解性
未确定
敏感性
对光敏感
密度
1.277 g/mL at 25 °C(lit.)
计算特性
精确分子量
275.04600
氢键供体数量
0
氢键受体数量
5
可旋转化学键数量
5
同位素质量
275.046
重原子数量
19
复杂度
348
同位素原子数量
0
确定原子立构中心数量
0
不确定原子立构中心数量
0
确定化学键立构中心数量
0
不确定化学键立构中心数量
1
共价键单元数量
1
疏水参数计算参考值(XlogP)
4.4
互变异构体数量
无
表面电荷
0
拓扑分子极性表面积
49.9A^2
海关数据
海关编码
29299000
海关数据
中国海关编码:
2931900090
概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
生产方法和用途
用途
在有机合成,医药合成及肽类化合物合成方面有广泛应用。叠氮化试剂,用于四苯卟啉-钴催化的烯烃的氮丙啶化。 也用作制备大环内酰胺和醛糖还原酶抑制剂的激活剂。也是重要的有机磷试剂。
相关文献
1.
Cutting edge of diphenyl phosphorazidate (DPPA) as a synthetic reagent – A fifty-year odyssey
Takayuki Shioiri,Kotaro Ishihara,Masato Matsugi Org. Chem. Front. 2022 9 3360
2.
1,2,3-Triazole-based sequence-defined oligomers and polymers
Xiaojun Wang,Xueyan Zhang,Shengtao Ding Polym. Chem. 2021 12 2668
3.
Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates
Qing Li,Xiaohua Sun,Xiaoqin Yang,Minghu Wu,Shaofa Sun,Xiuling Chen RSC Adv. 2019 9 16040
4.
Amino-functionalized iminocyclitols: synthetic glycomimetics of medicinal interest
Vimal Kant Harit,Namakkal G. Ramesh RSC Adv. 2016 6 109528
5.
Inhibition of O-GlcNAcase by a gluco-configured nagstatin and a PUGNAc–imidazole hybrid inhibitor
Bhagavathy Shanmugasundaram,Aleksandra W. Debowski,Rebecca J. Dennis,Gideon J. Davies,David J. Vocadlo,Andrea Vasella Chem. Commun. 2006 4372
6.
Triazolated calix[4]arenes from 2-azidoethylated precursors: is there a difference in the way the triazoles are attached to narrow rims?
Alexander Gorbunov,Julia Kuznetsova,Kirill Puchnin,Vladimir Kovalev,Ivan Vatsouro New J. Chem. 2019 43 4562
7.
The synthesis and ring-opening metathesis polymerization of glycomonomers
Lucy G. Weaver,Yogendra Singh,Paul L. Burn,Joanne T. Blanchfield RSC Adv. 2016 6 31256
8.
Self-assembly of heteroleptic dinuclear silver(i) complexes bridged by bis(diphenylphosphino)ethyne
Sarah Keller,Timothy N. Camenzind,Johannes Abraham,Alessandro Prescimone,Daniel H?ussinger,Edwin C. Constable,Catherine E. Housecroft Dalton Trans. 2018 47 946
9.
When phosphoryl azide meets mechanochemistry: clean, rapid, and efficient synthesis of phosphoryl amides under B(C6F5)3 catalysis in a ball mill
Lin-Yu Jiao,Xin-Hua Peng,Ze-Lin Wang,Nan Jia,Zhuo Li Catal. Sci. Technol. 2021 11 6659
参考资料
Reaxys RN
2058967
Beilstein
2058967
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