4,7,13,16,21,24-六氧-1,10-二氮双环[8.8.8]二十六烷 | 23978-09-8
中文名称:
4,7,13,16,21,24-六氧-1,10-二氮双环[8.8.8]二十六烷
英文名称:
2,2,2-Crypt
CAS No.:
23978-09-8
分子式:
C1 8 H3 6 N2 O6
分子量:
376.4882
名称和标识符
MDL
MFCD00005111
InChIKey
AUFVJZSDSXXFOI-UHFFFAOYSA-N
Inchi
1S/C18H36N2O6/c1-7-21-13-14-24-10-4-20-5-11-25-17-15-22-8-2-19(1)3-9-23-16-18-26-12-6-20/h1-18H2
SMILES
O1C([H])([H])C([H])([H])OC([H])([H])C([H])([H])N2C([H])([H])C([H])([H])OC([H])([H])C([H])([H])OC([H])([H])C([H])([H])N(C([H])([H])C([H])([H])OC([H])([H])C([H])([H])OC([H])([H])C2([H])[H])C([H])([H])C1([H])[H]
BRN
0620282
别名信息
- 中文别名 -
4,7,13,16,21,24-六氧-1,10-二氮双环[8.8.8]二十六烷
4,7,13,21,24-六氧杂-1,10-二氮杂双环[8,8,8]-二十六烷
2-脱氧-2-氟-D-葡萄糖相关物质A USP标准品
4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane 4,7,13,21,24-六氧杂-1,10-二氮杂双环[8,8,8]-二十六烷
4,7,13,16,21,24-六叠氮-1,10-二唑双环酮
4,7,13,16,21,24-六氧-1,10-二氮双环(8.8.8)二十六烷
4,7,13,16,21,24-六氧杂-1,10-二氮杂双环[8.8.8]二十六烷
克瑞吐菲
穴醚222
穴醚K222
4,7,13,16,21,24-六氧-1,10-二氮二环[8.8.8]二十六环
4,7,13,16,21,24-六氧-1,10-二氮双环[8.8.8]二十六
4,7,13,16,21,24-六氧-1,10-二叠氮双环[8.8.8]-二十六烷
涤纶切片
- 英文别名 -
4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane
4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]-hexacosane
Kryptofix 222
2,2,2-Crypt
4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo-[8.8.8]hexacosane
[2.2.2]cryptand
2.2.2-Kryptofix(R)
Cryptand 222
Cryptate 222
Cryptating agent 222
Cryptofix 222
Kriptofix 222
Kryptand 222
Kryptofix 222(R)
kryptofix(R)2.2.2
Kryptofix? 222
Ligand 222
Kryptofix® 222
Cryptand 2.2.2
Cryptand C 222
Crypt-2,2,2
Kryptofix Merck 222
C18H36N2O6
18V22YHN6G
AUFVJZSDSXXFOI-UHFFFAOYSA-N
AK111408
Kryptofix(R) 222, 98%
4,
物化性质
实验特性
LogP
-0.40700
PSA
61.86000
折射率
1.5700 (estimate)
水溶性
溶解
沸点
513.1°C at 760 mmHg
熔点
69.0 to 73.0 deg-C
闪点
144.2°C
颜色与性状
未确定
溶解性
未确定
敏感性
易吸潮
密度
1.1888 (rough estimate)
计算特性
精确分子量
376.25700
氢键供体数量
0
氢键受体数量
8
可旋转化学键数量
0
同位素质量
376.257337
重原子数量
26
复杂度
247
同位素原子数量
0
确定原子立构中心数量
0
不确定原子立构中心数量
0
确定化学键立构中心数量
0
不确定化学键立构中心数量
0
共价键单元数量
1
疏水参数计算参考值(XlogP)
-1
互变异构体数量
无
表面电荷
0
拓扑分子极性表面积
61.9
海关数据
海关编码
2934999090
海关数据
中国海关编码:
2934999090
概述:
2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
Summary:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
相关文献
1.
Metathesis of a UV imido complex: a route to a terminal UV sulfide
Rory P. Kelly,Marta Falcone,Carlos Alvarez Lamsfus,Rosario Scopelliti,Laurent Maron,Karsten Meyer,Marinella Mazzanti Chem. Sci. 2017 8 5319
2.
Cation assisted complexation of octacarbazolylphenyl substituted Zn(ii)-tetraphenylporphyrin with [2,2,2]cryptand
Galina M. Mamardashvili,Olga V. Maltceva,Nugzar Zh. Mamardashvili,Nguyen Tran Nguyen,Wim Dehaen RSC Adv. 2015 5 44557
3.
Aufbau vs. non-Aufbau ground states in two-coordinate d7 single-molecule magnets
Dylan Errulat,Katie L. M. Harriman,Diogo A. Gálico,Jeffrey S. Ovens,Akseli Mansikkam?ki,Muralee Murugesu Inorg. Chem. Front. 2021 8 5076
4.
Anion activation by the bulky perhydrotribenzo[2.2.2]cryptand in aqueous–organic two-phase systems and in low polarity media. A comparison with the anionic reactivity induced by [2.2.2,C14]cryptand
Dario Landini,Angelamaria Maia,Fernando Montanari,Franco Rolla J. Chem. Soc. Perkin Trans. 2 1981 821
5.
Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex
Mikiyas K. Assefa,Guang Wu,Trevor W. Hayton Chem. Sci. 2017 8 7873
6.
Fluoride complexation by bidentate silicon Lewis acids
Jan Horstmann,Mark Niemann,Katarína Berthold,Andreas Mix,Beate Neumann,Hans-Georg Stammler,Norbert W. Mitzel Dalton Trans. 2017 46 1898
7.
Potassium fluoride activation for the nucleophilic fluorination reaction using 18-crown-6, [2.2.2]-cryptand, pentaethylene glycol and comparison with the new hydro-crown scaffold: a theoretical analysis
Josefredo R. Pliego Org. Biomol. Chem. 2018 16 3127
8.
Theoretical design of new macrocycles for nucleophilic fluorination with KF: thiourea-crown-ether is predicted to overcome [2.2.2]-cryptand
Ellen V. Dalessandro,Josefredo R. Pliego Mol. Syst. Des. Eng. 2020 5 1513
9.
Single metal four-electron reduction by U(ii) and masked “U(ii)” compounds
Dieuwertje K. Modder,Chad T. Palumbo,Iskander Douair,Rosario Scopelliti,Laurent Maron,Marinella Mazzanti Chem. Sci. 2021 12 6153
10.
Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La2+ and Ce2+ are four electron reductants
Christopher M. Kotyk,Megan E. Fieser,Chad T. Palumbo,Joseph W. Ziller,Lucy E. Darago,Jeffrey R. Long,Filipp Furche,William J. Evans Chem. Sci. 2015 6 7267
参考资料
Reaxys RN
620282
Beilstein
620282